Food Safety & Environmental Stewardship

November 2002

FSES Advisory Council & Friends

~FSES Director

pumpkins“Magnitude of Residue Studies for Dimethenamid-P on  Winter Processing Squash”

Squash growers struggle to keep weeds from reducing squash yields and producing seeds that increase weed control costs in future crops. Summer annuals such as pigweed, lambsquarter, and nightshade can reduce squash yields by as much as 75%. Project Goal: Provide residue data for IR-4 and EPA to establish a tolerance and a regional label for dimethenamid-p in winter processing squash.

We have developed a dimethenamid-p method, and are currently validating the method per US EPA guidelines.  The field trial samples from OSU’s North Willamette research and extension station and Mt. Vernon, Washington will be arriving any day.  One of the study audits, the in-phase audit, will be November 8th.  We hope to avoid a storage stability study, and anticipate the project will be completed winter of 2003.  The storage stability study would add an additional month to the project timeline.  The project was funded in-part by the Oregon Minor Crop Association and Autumn Seed Co. of Oregon.  The data will be submitted to EPA through IR-4.  Special thanks goes to Ed Peachey and Bob McReynolds for hand-holding this project through occasional bumpy terrain.  Participants include: Oregon Minor Crop Association Com., Growers (Autumn Seed Co.), FSES Program, IR-4, EPA, BASF, ODA, OSU, and ARF.

 

Bioavailable Contaminants- Willamette River,

Newberg field sampling was underway spring/summer/fall 2002

The Newberg area on the Willamette river has shown, for over a decade, a high prevalence of skeletal deformities in fish. The FSES program is part of a larger team of OSU investigators examining this problem.  We are focusing on water physical and chemical conditions.  We were fortunate, to get into the field in 2002 for integrated sampling in time for spawning and early fish development.  For some chemical analytes we collected data every hour for 3 months (thank goodness for technology).  We are now in the process of analyzing all the samples and data.

Pictured below is Jennifer Schaeffer and Gene Johnson, pulling up about 80 lbs of sampling gear, here we are sampling bioavailable organic contaminants and heavy metals in the Willamette river.

Gene & Jen

New FSES faculty research assistant, Jennifer Schaeffer, learning to “pull her own weight” during field sampling in the Portland Harbor

Jen, BS Chemistry, most recently worked as a Quality Assurance Auditor for Argus Research a division of Charles River Laboratories, PA.  She is  learning about Oregon agriculture very quickly, (FYI: a close friend of hers works in the Oregon nursery business).

FSES Program
  Metolachlor runoff: Field study farmer modifications environ. results
  Selenium speciation -bioavailability in environmentally matrices, leading to determination of fate and transport processes
Pendimethalin-herbicide drift GLP

herbicide user v-organic farmer

Willamette River

Portland Harbor:

 PCBs, pesticides, PAHs, metals-fish

surface waters: bioavailability, effects of episodic events

Newberg:

bioavailable contaminants

McCormick & Baxter

Bioavailable PAH, Cu, Cr, As,  PCP

 

Pyrethrins

-clinical case

investigations EMT dept. medical toxicologist

  Dimethenamid-p in Squash, EPA residue registration study, GLP
  Tri-butyl tin speciation Portland Harbor, & bioavailable metals
Glyphosate-biochemical marker, round-up resistant weeds
Historical (500 yr.) Biomonitoring/tree - heavy metals by ICPMS isotope ratio
Willamette Valley-

(Pudding Rv & Calapooia Rv) Persistent Bioaccumulative Toxic Chemicals and Nutrients

land use and runoff & episodic events effects

Geographic Authentication of food origin

Oregon Blueberries,

Oregon Strawberries

Oregon Pears

California Pistachios

ALS Inhibitor herbicides-2-aminobutyric acid

  biochemical marker sub-lethal applications

 

Geographic Authenticity

Development of Chemical Profiling Techniques to Determine Geographic Origin of Food

We are currently working on two geographic authenticity projects.  One project funded by the Agricultural Research Foundation has focused on developing analytical chemical profiling techniques to determine if we can distinguish between Oregon fruit and South American and Mexican fruit.

We are also funded by the California Pistachio Commission to develop chemical profiling methods to distinguish between California and Middle East pistachios.  Product substitution in the European market, especially those from Iran and Turkey which have been miss-labeled as from California are of concern.  Roger Adams, new FSES faculty research assistant, is currently analyzing pistachios for trace metals.Angie Perez

Angie Heater, an OSU student, helps out with the Portland Harbor project, pictured here filling out some GLP paperwork. 

Angie most often though can be found working on the geographic authenticity project.  Her fluent Spanish has come in handy already, as she has secured samples from several South American locations.

WHY FSES

FSES Mission
The Food Safety and Environmental Stewardship Program at Oregon State University is a research program committed to providing the highest quality analytical laboratory research support for:

food quality assurance,

environmental integrity preservation, enhancement of agricultural production, and

recognition and dissemination of new knowledge.

~

Research Project Schematic

Displayed again, on the back page is a schematic of all the projects we were expecting to be involved with during 2002.  With only one exception, we have indeed managed all of these projects, many have been completed others are still in progress.

–  What a year  -

 

Oregonian

Determination of Geographic Origin is Important to the Food Industry

  • Enforcement options for the food industry
  • Protection of the consumer from overpayment
  • Protection of the consumer from deception
  • Protection of a grower’s market share
  • Protection of a grower’s reputation
  • Protection of a consumer’s confidence of food industry
  • Quality: sub-standard substitution
  • Safety: sanitation, chemical applications
  • Consumer’s preferences
  • Public information where food was grown
  • Processed food: raw material is variable

Progress!

Liquid Chromatograph-Mass Spectrometer (LC-MS/MS)

An account has been created at the Agricultural Research Foundation for funds to be gathered for the eventual purchase of a LC-MS/MS for the FSES program.

There is a need for a LC/MS for the FSES Program at OSU dedicated to food and environmental samples for quantitative analyses of pesticides, feed additives (vitamins, proteins, pharmaceuticals), aflatoxins, and other soluble chemicals. 

Environmental issues are inextricably linked to nearly all of the outstanding political and economic debates of our times, and there is no prospect that environmental issues will disappear in the future.  In order to meet this goal, it will be necessary for the FSES program to have the necessary equipment to perform these investigations.  Regulatory agencies use LC/MS as the technique of choice for most new pesticides and other soluble contaminants.  The LC/MS allows users to analyze for a very large list of analytes, as well, provides for excellent sensitivity (low detection limits).  If the program utilizes older less sensitive equipment (high detection limits), the data will be dismissed as “not adequate or usable”.  The result will be that the FSES program will be excluded from providing data to support/dispute investigative studies or initiating investigative studies within the FSES program mission.

Now that the account has been created (thanks Dorothy Beaton, ARF) we anticipate good things.

Contact Information:

Food Safety & Environmental Stewardship Program

http://emt.oregonstate.edu/extension/index.htm#fses

FSES Program Director:

Kim A. Anderson

Department of Environmental & Molecular Toxicology

1007 Agricultural Life Sciences Bldg

Oregon State University

Corvallis, OR 97331

541-737-8501

EMT Office 737-3791

FAX 541-737-0497